Influence of physicochemical melt treatment on structure and properties of AK7ch alloy microalloyed with Sr-Sc and Ti-B-Sr complexes

Authors

DOI:

https://doi.org/10.15802/tpm.2.2025.04

Keywords:

silumin, microalloying, hydrogen treatment, thermotemporal treatment, deformability, corrosion properties

Abstract

Purpose. The aim of  research is to determine the features of structure formation and property enhancement in the AK7ch alloy under the influence of microalloying with complex modifiers Sr-Sc and Ti-B-Sr, as well as physicochemical treatment in the liquid state. Methodology. The object of study was the AK7ch alloy of the base composition and microalloyed with Sr-Sc and Ti-B-Sr complexes in both the as-cast state and after hydrogen and thermotemporal melt treatments. Structural formation was investigated using metallographic analysis. The ultimate deformability was determined by an improved method for assessing the limiting deformation degree during rolling of wedge-shaped samples. Corrosion resistance, including general and intergranular corrosion susceptibility, was assessed using standard testing methods. Results. It was found that the combined physicochemical effect of microalloying with Sr-Sc and 20-minute hydrogen melt treatment increased the deformability of the AlSi7 alloy by 60%.  Ti-B-Sr addition and 30-minute thermotemporal melt treatment increased deformability by 46% compared to the original as-cast alloy. It was also established that microalloying with Ti-Sr-B and isothermal treatment for 30 minutes significantly enhance the corrosion resistance of the AK7ch alloy. Scientific novelty. The study proves the effectiveness of microalloying with Sr-Sc and Ti–B–Sr complexes in combination with hydrogen and thermotemporal melt treatments for improving the deformability of AK7ch alloy compared to the base composition. The positive effect of such treatments on the alloy’s general corrosion resistance was also confirmed. Practical significance. The research provides effective methods for enhancing the technological deformability and corrosion resistance of AK7ch aluminum alloy through microalloying with Sr–Sc and Ti–B–Sr complexes in combination with hydrogen or thermotemporal melt treatment. The proposed approaches significantly improve the alloy’s structure, which promotes increased corrosion resistance and overall reliability of finished products, especially in critical components used in mechanical engineering, aviation, and transport industries.

References

Kutsova V. Z., Pohrebna N. E., Khokhlova T. S. ta in. Aliuminii ta splavy na yoho osnovi [Aluminum and alloys based on it]. Dnipropetrovsk: Porohy, 2004. 136 s.

Chen, G.Q., Fu, G.S., Yang, K.H., Lin, C.S., 2020. Study on the Modification Effect of Al-Sr Master Alloy on A356 Aluminum Alloy. MSF 998, 3–8. https://doi.org/10.4028/www.scientific.net/msf.998.

Ishchenko A.Y. Svaryvaemye aiumynyevye splavy so skandyem [Weldable aluminum alloys with scandium]/ A.Y. Yshchenko, T.M. Labur. – K.: Kvits, 1999. – 116 s.

Kutsova V.Z., Aiupova T.A., Ambrazhei M.Iu. Vlyianye mykrolehyrovanyia Sr y Sc na fazovyi sostav y svoistva AK7ch [Influence of Sr and Sc microalloying on the phase composition and properties of AK7ch]/ Stroytelstvo, materyalovedenye, mashynostroenye // Sb. nauchn. tr. – Vyp. 41, ch.1. – Dnepropetrovsk, PHASA. – 2007. – S.18–30.

Refinement of eutectic grains by combined addition of strontium and boron in near-eutectic Al–Si alloys / Hengcheng Liao, Min Zhang, Qichang Wu, Huipin Wang and Guoxiong Sun // Scripta Materialia. – 2007. - No. 57.

Kutsova V.Z. Struktura y svoistva doevtektycheskykh sylumynov, modyfytsyrovannykh kompleksom Ti-B-Sr [Structure and properties of pre-eutectic silumins modified by the Ti-B-Sr complex] / V.Z. Kutsova, A.S. Elahyn, Ye.Y. Svynarenko // Metaloznavstvo ta termichna obrobka metaliv: Naukov. Ta inform. Zhurnal / PDABA, Dn-sk. – 2011.-No. 1-2 (52-53). – S. 310-318.

Vodneve rafinuvannia aliuminiievykh splaviv vid tverdykh nemetalevykh vkliuchen [Hydrogen refining of aluminum alloys from solid non-metallic inclusions] /F. M. Kotliarskyi, H. P. Borysov, V. I. Bielik ta in.// Protsesy lyttia. − 2008. − No. 4. − S. 48-55.

Mazur, V. Y. Upravlenye kachestvom sylumynovoho lytia s pomoshchiu termovremennoi obrabotky rasplava [Quality control of silumin casting using thermal treatment of the melt]/ Mazur, V. Y., Kapustnykova, S. V., Shportko, A. Yu., Bondarev, S. V. // Novi materialy i tekhnolohii v metalurhii ta mashynobuduvanni, 2012 (2), S. 47-49.ISSN 1607-6885

Kutsova V.Z. Vlyianye vodorodnoi obrabotky rasplava na strukturu y svoistva splava typa AK7ch [The effect of hydrogen treatment of the melt on the structure and properties of the AK7ch type alloy]/ V.Z. Kutsova, T.A. Aiupova // MTOM. – 2008. - No.4. – S. 50-61.

Kutsova V.Z. Vlyianye kompleksnoho modyfytsyrovanyia, termycheskoi obrabotky v zhydkom sostoianyy na strukturu y svoistva splava AK7ch [Effect of complex modification, heat treatment in the liquid state on the structure and properties of the AK7ch alloy] / V.Z. Kutsova, A.S. Elahyn // Novyny nauky Prydniprovia. – DVNZ PDABA, 2012. No.2. – S. 13-16.

FOUNDRY ALUMINUM ALLOYS COLD ROLLING / Dolzhanskyi A.M., Kutsova V.Z., Ayupova T.A., Storozhko K.D., Rybkin O.P. // Metaloznavstvo ta termichna obrobka metaliv. No.1 (2020). Dnipropetrovsk, PHASyA. – 2020. - P.55-61. DOI:10.30838/J.PMHTM.2413.260222.51.633

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Published

2025-06-30

How to Cite

Aiupova , T., Yelagin А., Kovzik , A., Bila , O., & Pohrebna , N. (2025). Influence of physicochemical melt treatment on structure and properties of AK7ch alloy microalloyed with Sr-Sc and Ti-B-Sr complexes. Theory and Practice of Metallurgy, (2), 30–35. https://doi.org/10.15802/tpm.2.2025.04

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